Showing posts with label fertilizer. Show all posts
Showing posts with label fertilizer. Show all posts

Monday, October 02, 2023

A Fatal Ammonia-Tanker Crash in Illinois

 

Around 5 p. m. on Friday, Sept. 29, a wreck on Interstate 70 between Effingham and Teutopolis, Illinois caused authorities to divert traffic from the interstate onto the older Route 40 that goes directly through the two towns.  Farming is the main business in that region, and among the vehicles diverted onto Route 40 that evening was a tanker truck carrying 7,500 gallons of anhydrous ammonia, which is a popular form of nitrogen fertilizer.

 

At 9:25 p. m., the truck overturned in a multiple-vehicle collision which is still being investigated by the National Transportation Safety Board (NTSB).  Because of the large toxic plume of ammonia that resulted, first responders evacuated about 500 people from northeast Teutopolis overnight, allowing them to return late Saturday.  Once rescuers were able to access the scene, it was found that five people had died, including two children under 12.  It was not clear at this writing whether the victims died of ammonia inhalation or from effects of the crash itself, but five survivors were taken to a local hospital as well.

 

Every day, hundreds of ammonia tankers travel between distribution points on their way to supplying farmers with what many consider to be an essential and economical fertilizer.  Ammonia gas, which consists of one atom of nitrogen and three of hydrogen, is a colorless acrid-smelling substance that boils at 28 below zero Fahrenheit.  (The household bottles of ammonia that can be found in grocery stores are actually weak solutions of the gas in water.)  Before Fritz Haber developed a high-pressure process to synthesize ammonia directly from hydrogen and nitrogen in the air around 1910, ammonia was obtained mainly by distilling animal urine, a messy and expensive job at best.  After World War II-era chemical plants found themselves with an overcapacity of ammonia plants once the war ended, the price dropped to the point that direct injection of the gas into soil at a depth of six inches or more became a fast and economical means of applying nitrogen fertilizer.  Since then, an entire anhydrous-ammonia infrastructure has grown up to deliver the substance to millions of acres of farmland, usually without incident.

 

But every now and then something goes wrong, as it did last week in Teutopolis.  Despite the best efforts of mechanical designers to make tanker trucks safe, collisions can sever connecting pipes and cause leaks, which is apparently what happened last Friday.  Ammonia as a gas is lighter than air, but if enough is released near the ground it will form a suffocating cloud that cannot be seen.  This is why the authorities took the prudent precaution of evacuating part of Teutopolis once the nature of the accident became clear. 

 

In addition to being toxic at concentrations above a few parts per million, ammonia is explosive when present at air concentrations higher than about 15%.  So if you escape being suffocated by it, you could instead be blown to bits. 

 

It's surprising that there aren't more accidents involving anhydrous ammonia, but when it is used in properly designed equipment by trained operators who know how dangerous it is, it can be transported safely all the way from the factory to the soil, where it is quickly absorbed by complex chemicals and biological materials and becomes available to fuel plant growth. 

 

At the same time, it is a highly unnatural process characterized by many features that we associate with modern industrial culture:  large-scale concentrations of products, complex distribution networks, and use in largely monoculture farms (all corn or all wheat, for example).  All these things go against the grain (so to speak) of the small-farming idea that each farm should be its own ecosystem, recycling manure to the soil, which grows the food for the animals, and so on. 

 

For whatever reason, we as a culture seem to be happy with (or at least blissfully unaware of) the forces and compromises involved in the kind of industrial-scale agriculture that we have.  The cheapest food, if externalities such as ammonia accidents are ignored, will always be the mass-produced type made with the minimum amount of labor using the largest economies of scale.  But externalities are not nothing, and the problems that large-scale agriculture causes, ranging from pollution to alleged animal cruelty to obesity, don't often have dollar prices attached to them. 

 

If we were losing hundreds of people a year in anhydrous-ammonia accidents, the issue might come into public consciousness to the extent that some might at least question the propriety of fertilizing plants this way.  But as it is, such mishaps are so unusual as to be newsworthy in themselves.  While it is tragic any time anybody is killed, we may find that the people who lost their lives in this accident were killed by the consequences of the collision itself and not the ammonia that was released afterwards.  Either way, it seems that we as a nation are willing to accept some hazards—namely, having tons of anhydrous ammonia rolling around on highways and railroads—in exchange for the advantages that the process confers on farming.

 

I recently read a book with a title that my wife remarked was one of the longest for a non-fiction book she's seen:  The End is Near And It's Going To Be Awesome:  How Going Broke Will Leave America Richer, Happier, and More Secure.  Its author, Kevin Williamson, has a background in economics, but he's not one of these wonky numbers-only types who reduces every human to a rational utility optimizer.  His main point is that when society wants to do something, the best way to do it is for interested people to get together and figure it out for themselves.  Only as a last resort should we invoke the power of politics to pass laws about the issue.  The reason is that law is a blunt instrument that is usually wielded by the powerful to exploit the less powerful, and no matter how well-intended the action is to start with, the effect usually ends up making the strong better off at the expense of the less fortunate.

 

So while we await the results of the Teutopolis accident investigation, let's hope it doesn't lead to a call for new regulations on the anhydrous-ammonia industry.  From all appearances, that enterprise seems to be handling things pretty well on its own, and I hope the tank-truck makers learn from this accident how to prevent more like it in the future.

 

Sources:  I referred to articles on the Teutopolis accident at https://www.cnn.com/2023/09/30/us/illinois-anhydrous-ammonia-leak/index.html

and https://abc7chicago.com/teutopolis-fatal-crash-evacuation-anhydrous-leak-ammonia/13847580/.  Kevin D. Williamson's The End is Near And It's Going To Be Awesome was published in 2013 by HarperCollins.

Monday, May 05, 2014

West One Year Later: Will It Happen Again?


On April 22, the U. S. Chemical Safety Board held a news conference to present its recommendations about how to prevent another disaster such as the one in West, Texas that killed fifteen, injured over 200, and caused millions of dollars of property damage on April 17, 2013.  So far, not a lot has changed in terms of federal or state regulations pertaining to ammonium nitrate, the fertilizer chemical that exploded on that fateful day.  But a fertilizer trade organization has issued a set of recommendations that, if followed, will go some distance toward reducing the chances that another disastrous accident involving the chemical will happen again.

As long ago as 2002, the Chemical Safety Board recommended that ammonium nitrate be included in OSHA (Occupational Safety and Health Administration) and EPA (Environmental Protection Administration) regulatory programs, but these agencies have not yet chosen to act on these recommendations.  Ammonium nitrate falls in a gray area between chemicals such as nitroglycerin or TNT that are clearly dangerous, and others such as sand that are harmless.  Under most circumstances, ammonium nitrate can be handled with little or no risk.  But under certain combinations of heat, pressure, and/or shock, the chemical detonates, transforming many tons of solid matter into hot gases that expand explosively, as they did in West. 

In response to the West accident a trade organization called The Fertilizer Institute issued a fourteen-page booklet to its members last February with the title "Safety and Security Guidelines for the Storage and Transportation of Fertilizer Grade Ammonium Nitrate at Fertilizer Retail Facilities."  The title does not promise exciting reading, though the legalese and lengthy definitions of different types of ammonium-nitrate fertilizer are enlivened by color photos of fertilizer manufacturing and handling installations.  The pamphlet summarizes most of the precautions which, if followed, would have gone a long way toward preventing the West disaster. 

These measures fall into two categories: (1) ways to prevent ammonium nitrate from exploding in the first place, and (2) ways to avert death and destruction if a fire breaks out where ammonium nitrate is stored, and the stuff explodes anyway.  The prevention measures are more or less what you'd expect:  things like storing the material in non-combustible bins, rather than wooden ones as were used in the West firm; installing sprinkler systems or other fire-prevention and fire-fighting facilities; and treating places where ammonium nitrate is stored like flammable-material storage areas (no-smoking signs, no sparks or flames nearby, etc.).  Because an exact cause of the fire at West that led to the explosion may never be found, we cannot know for certain if these precautions would have prevented the tragedy.  But obviously, they are good things to do, and if fertilizer retailers around the country follow these prevention guidelines, the chances of another such accident will be reduced.

The second category of recommendations is more problematic.  It involves informing the wider community, including first-responder agencies, that ammonium nitrate is stored in the facility and should be treated with extra caution.  By the nature of the business, many fertilizer retailers are located in semi-rural or thinly populated areas.  These locales are often served by volunteer fire departments, and while volunteer firemen theoretically should be trained as well as full-time paid firefighters, the reality is that their training may be on the sketchy side.   The Chemical Safety Board concluded that the first responders in West did not know of the dangers presented by the large quantity of ammonium nitrate stored at the plant where they responded to what appeared at first to be an ordinary fire, and were much too close for safety.  Consequently, when the plant exploded, most of the people who died were firefighters.  The guidance handbook says "The rule of thumb is if outside emergency responders are necessary, do not fight AN [ammonium nitrate] fires.  For fires that have engaged AN, plans should focus on evacuation of the area."  In other words: don't fight, run. 

While the trade-association brochure's advice is good, it has no legal standing, and firms are free to adopt its recommendations or ignore them.  Simply as a matter of asset protection, I would hope that fertilizer retailers who sell ammonium nitrate are at least considering an upgrade of unsafe storage facilities, and the brochure provides good guidelines as to how to carry this out.  However, the informational side of the recommendations may be harder to implement.  A business owner may feel some reluctance in volunteering the information to local authorities that his facility harbors material that might reduce a wide swath of his neighborhood to rubble.  Nevertheless, there may be courageous and conscientious owners who will do such things. 

Both the Chemical Safety Board and various other authorities have called for tighter compulsory regulation of ammonium nitrate storage and transportation.  This is a political as well as a technical and ethical matter, and politics these days tends to go to polarized extremes.  On the one hand are those who favor centralized uniform federal regulations for all sorts of things, including ammonium nitrate.  On the other hand, a prominent plank in the Tea Party platform is the idea that government regulations have gone too far and are stifling free enterprise and economic growth.  The regulations contemplated with regard to ammonium nitrate vary from rules about how the stuff is stored to rules about notification and training of local first responders.  It seems to me that sensible regulations requiring the exchange of information, perhaps implemented by some sort of web-based registry, would be the least costly way to make sure that at a minimum, any firefighters responding to an ammonium-nitrate fire would know what they are dealing with and would take appropriate precautions. 

One way of dealing with this information problem is by the use of fire codes.  However, the state of Texas has a strong history of anti-regulatory bias.  In fact, counties with low population density in Texas are actually prohibited by state law from enacting fire codes at all.  So around July and December, you see roadside fireworks stands popping up for a few weeks with nary a concern for any safety beyond the immediate self-preservation of the owners in case a customer drops a burning cigarette. 

So far, the only concrete public action toward preventing more ammonium-nitrate fertilizer disasters has been the Fertilizer Institute's brochure.  While they deserve credit for their efforts, only time will tell whether enough has changed to keep another fertilizer plant from blowing up, or to save lives if it does.

Sources:  The news conference in Dallas on Apr. 22, 2014 held by the Chemical Safety Board was summarized by a UPI report at http://www.upi.com/Top_News/US/2014/04/22/US-investigators-Better-regulation-could-have-prevented-deadly-fertilizer-explosion/4731398190424/.  The Chemical Safety Board's own statements at the conference can be downloaded at http://www.csb.gov/assets/1/16/Statement_-_News_Conference_(Final).pdf.  The Fertilizer Institute recommendations can be found at http://www.tfi.org/ammonium_nitrate_guidelines.  And I blogged on the West explosion previously on Apr. 22 and May 20, 2013.